Deactivation mechanism and regeneration study of Zn/HZSM-5 catalyst in ethylene transformation
نویسندگان
چکیده
The purpose of this study is to identify the deactivation mechanism(s) that occurs during aromatization dilute ethylene at 500 °C on Zn/H-MFI catalyst. More than 15 catalysts, with a Zn/H+ molar ratio ranging from 0 (H-ZSM5) 1.8 (Zn/H-ZSM5), were prepared by wet impregnation. Deactivation does not result Zn sublimation, but coking. function and coke deposition can be modelled simple exponential laws. Moreover, balance between Lewis (Zn) Brønsted (H+) acid sites good descriptor for predicting catalyst stability. poisoning has similar impact diminution micropore volume as well reduction number sites. best suited describing volume.
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ژورنال
عنوان ژورنال: Applied Catalysis A-general
سال: 2021
ISSN: ['0926-860X', '1873-3875']
DOI: https://doi.org/10.1016/j.apcata.2020.117976